SYNTHESIS OF ALKYL N-CYANO-N-SUBSTITUTED CARBAMATES AND N, N-DISUBSTITUTED CYANAMIDES1

…, T Schafer, PG Ruminski, JJ D'amico

Index: Suba, Lydia; Schafer, Tann; Ruminski, Peter G.; D'Amico John J. Phosphorus and Sulfur and the Related Elements, 1987 , vol. 29, p. 219 - 226

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Abstract

Abstract The reactions of S, S'methyl cyanodithioimidocarbonate with potassium hydroxide in alkyl or benzyl alcohol furnished the O-alkyl and benzyl O-potassium cyanoimidocarbonates (1–5). The reaction of the potassium salts (1, 3, or 4) with a 10% excess of alkyl, allyl or benzyl halides afforded the unknown titled carbamates (6–17). The reaction of 2 with 10% excess benzyl bromide or 5 with 10% excess methyl iodide gave ...