ortho??Magnesiation of Boron??Substituted Benzenes by Using (TMP) 2Mg

…, Y Onoue, O Harada, Y Yamamoto

Index: Kawachi, Atsushi; Nagae, Saori; Onoue, Yasuhiro; Harada, Osamu; Yamamoto, Yohsuke Chemistry - A European Journal, 2011 , vol. 17, # 29 p. 8005 - 8008

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Citation Number: 6

Abstract

The ortho-metalation (hydrogen–metal exchange) of aromatic compounds assisted by heteroatom-containing functional groups is one of the most efficient methods for the transformation of aromatic compounds.[1] Among a variety of ortho-directing groups developed so far, good ortho-directing groups have two essential features. The first is the coordinating ability to the metal through the lone pair electrons on the heteroatom, which ...