Journal of organometallic chemistry

Synthesis and relative stability of five-and six-membered S-functional derivatives of 1, 3-thiasilacycloalkanes

EN Suslova, AI Albanov, BA Shainyan

Index: Suslova, Elena N.; Albanov, Aleksandr I.; Shainyan, Bagrat A. Journal of Organometallic Chemistry, 2003 , vol. 677, # 1-2 p. 73 - 79

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Citation Number: 11

Abstract

Oxidation, imidation, and S-methylation reactions of five-and six-membered 1, 3- thiasilacycloalkanes have been examined under various conditions. The S-functional derivatives of 1, 3-thiasilacycloalkanes undergo solvolytic Si C (S) bond cleavage in protic media. The ease of the ring opening depends on the S-functionality and on the ring size.