Kinetics of reactions of chlorinated vinyl radicals (CH2CCl and C2Cl3) with molecular oxygen
JJ Russell, JA Seetula, D Gutman…
Index: Russell; Seetula; Gutman; Senkan Journal of physical chemistry, 1989 , vol. 93, # 5 p. 1934 - 1938
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Citation Number: 35
Abstract
The kinetics of the reactions of CH2CCl and C2C13 radicals with O2 have been studied in a tubular flow reactor coupled to a photoionization mass spectrometer in the temperature range 298-648 K. Radicals were produced by the homogeneous photolysis of a suitable precursor using an excimer laser. The observed or indicated reaction mechanisms as well as the rate constants, which were measured as a function of density and temperature, ...
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