Determination of the C4 H Bond Dissociation Energies of NADH Models and Their Radical Cations in Acetonitrile

…, Q Li, T Ai, JY Lu, Y Yang, JP Cheng

Index: Zhu, Xiao-Qing; Li, Hai-Rong; Li, Qian; Ai, Teng; Lu, Jin-Yong; Yang, Yuan; Cheng, Jin-Pei Chemistry - A European Journal, 2003 , vol. 9, # 4 p. 871 - 880

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Citation Number: 104

Abstract

Abstract Heterolytic and homolytic bond dissociation energies of the C4 [BOND] H bonds in ten NADH models (seven 1, 4-dihydronicotinamide derivatives, two Hantzsch 1, 4- dihydropyridine derivatives, and 9, 10-dihydroacridine) and their radical cations in acetonitrile were evaluated by titration calorimetry and electrochemistry, according to the four thermodynamic cycles constructed from the reactions of the NADH models with N, N, ...

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