Journal of the American Chemical Society

The Chemistry of the Acetylenes. I. The Preparation of 1-Heptyne by Dehalogenation Methods

GB Bachman, AJ Hill

Index: Bachman; Hill Journal of the American Chemical Society, 1934 , vol. 56, p. 2730

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Citation Number: 13

Abstract

Two series of dehalogenation experiments were run: the one in the vapor phase using soda lime, the other in the liquid phase using potassium hydroxide suspended in mineral oi1. l Attempts to improve the yields obtained previously2 in the vapor phase method were only partially successful, and a series of experiments on the heat stability of heptyne indicated the probable futility of further efforts in this direction. Liquid phase dehalogenation of 1- ...