Oxidative Bromination of Aromatic Amides using Sodium Perborate as Oxidant

JR Hanson, S Harpel, ICR Medina…

Index: Hanson, James R.; Harpel, Simone; Medina, Inmaculada C. Rodriguez; Rose, Dorian Journal of Chemical Research, Synopses, 1997 , # 11 p. 432 - 433

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Citation Number: 7

Abstract

The oxidative bromination of aromatic amides is an attrac- tive, mild alternative to the more widely used bromine in glacial acetic acid.1 Recently the oxidative bromination of aromatic compounds has been described using potassium bromide, hydrogen peroxide and various metal-oxo com- pounds as catalysts.2–7 The use of vanadium(V) and molyb- denum(VI) compounds as catalysts has been examined in the context of models for bio-halogenation. The ...