Organic sulfur chemistry. 42. Sulfur-sulfur bond cleavage processes. Selective desulfurization of trisulfides
DN Harpp, RA Smith
Index: Harpp, David N.; Smith, Roger A. Journal of the American Chemical Society, 1982 , vol. 104, # 22 p. 6045 - 6053
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Citation Number: 70
Abstract
Abstract: The selectivity of sulfur removal in the desulfurization of trisulfides by tertiary phosphorus compounds has been investigated in detail. A mechanistic rationalization is proposed to account for central/terminal sulfur extrusion variation as a function of substrate structure and solvent polarity.
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