Vinyl Proton Abstraction during Metalation of α-Olefins
CD Broaddus, TJ Logan, TJ Flautt
Index: Broaddus,C.D. et al. Journal of Organic Chemistry, 1963 , vol. 28, p. 1174 - 1179
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Citation Number: 19
Abstract
The acidic products obtained from metalation and subsequent carbonation of 1-dodecene are shown to vary with time. At short reaction times 2-tridecenoic acid, arising from metalation at the terminal vinylic position, predominates. At longer reaction times the major producta are &-punsaturated acids, due to metalation at the allylic position. The precursor of 2-tridecenoic acid, 1-sodio-1-dodecene, waa shown to be stable to the metalation ...
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