Chemistry–A European Journal

Comparative Study of Metal??Catalyzed Iminations of Sulfoxides and Sulfides

O García Mancheño, C Bolm

Index: Mancheno, Olga Garcia; Bolm, Carsten Chemistry - A European Journal, 2007 , vol. 13, # 23 p. 6674 - 6681

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Citation Number: 43

Abstract

Abstract A comparative study of the imination of sulfur compounds with various metal catalysts in combination with isolated or in situ generated iminoiodinanes (PhI [DOUBLE BOND] NR) as nitrogen sources is presented. The influence of the metal catalyst towards the imination of a variety of substituted sulfoxides has been evaluated. Moreover, the effect of the different oxidation states of sulfur on the reactivity and selectivity of the nitrogen ...