Reaction of N-(triorganosilylmethyl) dialkylamines with benzyne

Y Sato, T Toyooka, T Aoyama…

Index: Sato,Y. et al. Journal of Organic Chemistry, 1976 , vol. 41, p. 3559 - 3564

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Citation Number: 24

Abstract

Silicon has a high affinity for ylide carbanions and exerts a stabilizing effect on these carbanions. lJ Phosphorus, arsenic, and sulfur ylides having a silicon substituent directly attached to the carbanion have been synthesized as distillable The stabilizing effect of silicon upon a nitrogen ylide is not well investigated. In an earlier paper4 we reported that the reaction of N-(trimethylsilylmethy1) dimethylamine (la) with benzyne gave ...