Benzylsulfanyloxazolines in palladium-catalyzed cross-coupling reactions: A novel approach to chiral oxazolines
…, A Tatibouet, F Suzenet, P Rollin, G Guillaumet
Index: Leconte, Nicolas; Pellegatti, Laurent; Tatibouet, Arnaud; Suzenet, Franck; Rollin, Patrick; Guillaumet, Gerald Synthesis, 2007 , # 6 p. 857 - 864
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Abstract
Abstract Various 2-benzylsulfanyl-1, 3-oxazolines were synthesized and engaged in a copper-promoted palladium-catalyzed cross-coupling reaction with a range of organoboryl and organostannyl reagents to produce 2-aryl-or 2-hetaryl-substituted oxazolines. Protected and unprotected carbohydrate backbones were shown to be compatible with the reaction conditions. This approach opens a new versatile access to chiral oxazoline structures.
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