Electroreductive silylation of activated olefins using a reactive metal anode
…, H Nakahiro, K Sanemitsu, T Hirashima, I Nishiguchi
Index: Ohno; Nakahiro; Sanemitsu; Hirashima; Nishiguchi Tetrahedron Letters, 1992 , vol. 33, # 38 p. 5515 - 5516
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Citation Number: 19
Abstract
Abstract Electroreductive silylation of α, β-unsaturated esters, nitriles and ketones in the presence of Me 3 SiCl using a reactive metal anode (Mg, Zn, Al) in an undivided cell afforded the corresponding β-silyl compounds offering a valuable method for introduction of a silyl group into activated olefins.
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