New Cyclohexadienone Derivatives: Preparation and Chiral Discrimination in High??Pressure Diels–Alder Cycloadditions

…, R Wartchow, E Winterfeldt, YS Wong

Index: Tran-Huu-Dau, Marie-Elise; Wartchow, Rudolf; Winterfeldt, Ekkehard; Wong, Yung-Sing Chemistry - A European Journal, 2001 , vol. 7, # 11 p. 2349 - 2369

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Citation Number: 50

Abstract

Abstract A wide range of cyclohexadienones has been synthesised in order to study their reactivity and their regio-and stereoselectivity with the enantiopure diene 1 under high- pressure conditions. Computational investigations were used to point out some parameters which affect the reactivity in this high chiral discrimination process. In addition, the resulting [4+ 2] cycloadducts allowed the preparation of new polyfunctional cyclohexenone ...