Oxygen-18-labeling evidence against a hexacoordinate phosphorus intermediate in the alkaline hydrolysis of ethyl ethylene phosphate

DG Gorenstein, K Taira

Index: Gorenstein, David G.; Taira, Kazunari Journal of the American Chemical Society, 1982 , vol. 104, # 22 p. 6130 - 6132

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Citation Number: 21

Abstract

D, O) at room temperature, and the solution was quickly frozen in an acetone/dry ice bath. To the almost frozen solution, was carefully added 66.6 FL of 36 N H2S04. The pH-2 solution was added to a tris-base buffer solution. Up to this point everything was carried out within a minute. Some inorganic precipitate was filtered through a nitric acid and EDTA solution treated disposable pipet plugged with EDTA-treated cotton and Chelex-100 (Bio-Rad) ion ...