Tetrahedron

A Schmidt route to 1-azabicyclo [xy 0] alkanes: a comparison of carbocation stabilizing groups

WH Pearson, R Walavalkar

Index: Pearson, William H; Walavalkar, Rajesh Tetrahedron, 2001 , vol. 57, # 24 p. 5081 - 5089

Full Text: HTML

Citation Number: 28

Abstract

The intramolecular Schmidt reactions of tertiary alkyl, tertiary benzylic, tertiary propargylic, and tertiary allylic carbocations with tethered azides are reported. Using product analysis and deuterium labeling studies, the role of cation rearrangement prior to Schmidt reaction is reported.