Heterometallic CoIII4FeIII2 Schiff Base Complex: Structure, Electron Paramagnetic Resonance, and Alkane Oxidation Catalytic Activity

…, LS Shul'pina, J Jezierska, A Ozarowski…

Index: Nesterov, Dmytro S.; Pombeiro, Armando J. L.; Chygorin, Eduard N.; Kokozay, Volodymyr N.; Bon, Volodymyr V.; Boca, Roman; Kozlov, Yuriy N.; Shul'Pin, Georgiy B.; Shul'Pina, Lidia S.; Jezierska, Julia; Ozarowski, Andrew Inorganic Chemistry, 2012 , vol. 51, # 16 p. 9110 - 9122,13

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Citation Number: 61

Abstract

We have found that a novel heterometallic Co/Fe Schiff base complex possesses a number of unique features, among them an outstanding activity toward oxidation of hydrocarbons with H2O2, under mild conditions: a TON of 3.6× 103, yield of 46%, and TOF of 1.12× 104 h− 1 were attained for cycloalkanes.