Mono-and bis-acrolein derivatives by reliable and efficient one-step methylenation of aldehyde precursors
K Basu, J Richards, LA Paquette
Index: Basu, Kallol; Richards, Jonathan; Paquette, Leo A. Synthesis, 2004 , # 17 p. 2841 - 2844
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Abstract
Abstract A series of aldehydes carrying different functional groups was transformed directly into the α-methylene derivatives. Dialdehydes behaved comparably at both active sites. When keto aldehydes are involved, excellent levels of chemoselectivity are observed, with the ketone substructures exhibiting no sign of reactivity.
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