Bulletin of the Chemical Society of Japan

Syntheses and the Beckmann Fission of Cyclic α-Hydroxyimino Ketones

M Kataoka, M Ohno

Index: Kataoka,M.; Ohno,M. Bulletin of the Chemical Society of Japan, 1973 , vol. 46, p. 3474 - 3477

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Citation Number: 11

Abstract

A convenient method for the preparation of α-hydroxyimino cycloalkanones has been established by the reaction of cycloalkanones and nitrosyl chloride. ω-Cyanocarboxylic acids or their derivatives were obtained in good yield by the Beckmann rearrangement of these α-hydroxyimino ketones.