One??Pot Synthesis of Pyridyltellurium Derivatives from a Reaction with Isopropylmagnesium Chloride and X??ray Crystal Structures of Various Pyridyl Ditellurides

…, V Arora, TM Klapötke, MJ Crawford

Index: Bhasin, Kuldip K.; Arora, Veena; Klapoetke, Thomas M.; Crawford, Margaret-Jane European Journal of Inorganic Chemistry, 2004 , # 24 p. 4781 - 4788

Full Text: HTML

Citation Number: 13

Abstract

Abstract A one-pot synthesis of various symmetrical and unsymmetrical 2-pyridyl-, 2-bromo- 5-pyridyl-, and 2, 5-dibromo-3-pyridyltellurium compounds has been carried out, at room temperature, by selective single bromine-magnesium exchange of 2-bromo-, 2, 5-dibromo- and 2, 3, 5-tribromopyridine, respectively, with isopropylmagnesium chloride. This exchange reaction gives the corresponding pyridylmagnesium chlorides, which, upon insertion of ...