Thermal decomposition of CF3O2NO2

A Mayer-Figge, F Zabel, KH Becker

Index: Mayer-Figge, A.; Zabel, F.; Becker, K. H. Journal of Physical Chemistry, 1996 , vol. 100, # 16 p. 6587 - 6593

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Citation Number: 17

Abstract

The unimolecular decomposition rate constant of CF3O2NO2 has been measured in detail as a function of temperature, pressure, and collision partner (M= N2, O2, NO). Temperatures were between 264 and 297 K, and total pressures ranged from 3 to 1013 mbar. The first- order decay of CF3O2NO2 in the presence of excess NO was followed in a temperature- controlled DURAN glass chamber by long-path IR absorption, using the absorption bands ...