2D 4.8 2 Network with threefold parallel interpenetration from nanometer-sized tripodal ligand and lead (ii) nitrate

…, J Fan, T Okamura, HF Zhu, XM Ouyang…

Index: Wan, Shuang-Yi; Fan, Jian; Okamura, Taka-Aki; Zhu, Hui-Fang; Ouyang, Xing-Mei; Sun, Wei-Yin; Ueyama, Norikazu Chemical Communications, 2002 , # 21 p. 2520 - 2521

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Citation Number: 54

Abstract

Reaction of nanometer-sized tripodal ligand 2, 4, 6-tris [4-(imidazol-1-ylmethyl) phenyl]-1, 3, 5-triazine (timpt) with lead (II) nitrate affords a novel polycatenated structure containing three interpenetrating 4.82 networks, in which the lead (II) atom has a hemidirected coordination geometry and a stereochemically active lone pair of electrons.