Phosphane??Free Hiyama Cross??Coupling of Aryl and Heteroaryl Halides Catalyzed by Palladium Nanoparticles in Ionic Liquids
C Premi, N Jain
Index: Premi, Chanchal; Jain, Nidhi European Journal of Organic Chemistry, 2013 , # 24 p. 5493 - 5499
Full Text: HTML
Citation Number: 9
Abstract
Abstract Palladium nanoparticles (NPs) 2–5 nm in size and preformed by thermal reduction in nitrile-functionalized 3-(3-cyanopropyl)-1-methyl-1H-imidazol-3-ium hexafluorophosphate {[CN-bmim] PF 6} act as an in situ catalyst for carbon–carbon bond-forming reactions of aromatic and heterocyclic halides with aryl-and vinyltrimethoxysilanes. A variety of biphenyl derivatives, substituted styrenes, and aromatic heterocycles were obtained in 76 to 98% ...
Related Articles:
[Janz, Kristin; Kaila, Neelu Journal of Organic Chemistry, 2009 , vol. 74, # 22 p. 8874 - 8877]
Synthesis and reactivity of pentavalent biphenyl-2, 2′-ylenebismuth derivatives
[Fedorov, Alexey Yu.; Finet, Jean-Pierre Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 22 p. 3775 - 3778]
[Wawrzyniak, Piotr; Heinicke, Joachim Tetrahedron Letters, 2006 , vol. 47, # 50 p. 8921 - 8924]
Divergent reaction pathways for phenol arylation by arynes: synthesis of helicenes and 2-arylphenols
[Truong, Thanh; Daugulis, Olafs Chemical Science, 2013 , vol. 4, # 1 p. 531 - 535]
Obsevations on the cleavage of the bismuth–carbon bond in Bi V compounds: a new arylation reaction
[Barton, Derek H. R.; Lester, David J.; Motherwell, William B.; Papoula, M. Teresa Barros Journal of the Chemical Society, Chemical Communications, 1980 , # 5 p. 246 - 247]