Rearrangement and cleavage processes in crowded cyclohexadienyl carbonium ions

KH Lai, B Miller

Index: Lai,K.-H.; Miller,B. Journal of Organic Chemistry, 1972 , vol. 37, # 15 p. 2505 - 2508

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Citation Number: 3

Abstract

CH, CH3 12 13 below). In contrast, rearrangement of 9 in refluxing benzene in the presence of Florisil gave three products in the ratio 7: 20: 73. These were isolated by preparative vpc. The major product was found to be 11. The product present in lowest yield was assigned the structure 12, and the product obtained in 20% yield was assigned structure 13.