Tetrahedron Letters

A facile method of transesterification using phosphorus ylid

S Hashimoto, I Furukawa, T Kuroda

Index: Hashimoto, Shizunobu; Furukawa, Isao; Kuroda, Tomoyuki Tetrahedron Letters, 1980 , vol. 21, p. 2857 - 2860

Full Text: HTML

Citation Number: 11

Abstract

Abstract The transesterification of carboxylic esters catalyzed with phosphorus ylid under neutral and mild conditions has been investigated. The reactions of esters having an electron withdrawing group with methanol proceeded rapidly and with high yield, whereas the reverse reactions proceeded slowly or not at all.

Related Articles:

Oxone-Mediated Oxidative Cleavage of β-Keto Esters and 1, 3-Diketones to α-Keto Esters and 1, 2-Diketones in Aqueous Medium

[Stergiou, Anastasios; Bariotaki, Anna; Kalaitzakis, Dimitris; Smonou, Ioulia Journal of Organic Chemistry, 2013 , vol. 78, # 14 p. 7268 - 7273]

Novel syntheses of oxamides, oxamates and oxalates from diisopropenyl oxalate

[Neveux, Muriel; Bruneau, Christian; Lecolier, Serge; Dixneuf, Pierre H. Tetrahedron, 1993 , vol. 49, # 13 p. 2629 - 2640]

Hydrocondensation of CO2

[Journal of Organometallic Chemistry, , vol. 221, # 1 p. 111 - 116]

Kinetic investigation of the mixed-metal bimolecular reductive eliminations in the reactions of EtOC (O) CH2M (CO) n or EtOC (O) M (CO) n (M= Co, n= 4; M= Mn, n= 5) …

[Organometallics, , vol. 4, p. 1347 - 1350]

A facile method of transesterification using phosphorus ylid

[Tetrahedron Letters, , vol. 21, p. 2857 - 2860]

More Articles...