Bis [bis (F-methyl) sulfimide], N-chlorobis (F-methyl) sulfimide, and N-fluorobis (F-methyl) sulfimide

RC Kumar, JM Shreeve

Index: Kumar, Ramesh C.; Shreeve, Jean'ne M. Journal of the American Chemical Society, 1981 , vol. 103, # 8 p. 1951 - 1952

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Citation Number: 9

Abstract

Abstract: The first member of a new class of stable sulfimides, bis [bis (F-methyl) sulfimide],(CF3) 2S= NN= S (CF3) 2, results from the photolysis of (CF3), S= NC1. The latter is prepared by reacting (CF3) $= NH with ClF in the presence of CsF. Under similar conditions,(CF3) $= NH reacts with SF4 to give (CF,), S= NF.

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