Generation of alkoxy radicals from N-alkoxypyridinethiones

ALJ Beckwith, BP Hay

Index: Beckwith, Athelstan L. J.; Hay, Benjamin P. Journal of the American Chemical Society, 1988 , vol. 110, # 13 p. 4415 - 4416

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Citation Number: 80

Abstract

@-Fission and hydrogen-atom abstraction, both inter-and intramolecular, are important characteristic reactions of alkoxy radicals.'. 2 Such processes play a key role in various synthetically important transformations including, inter the Barton rea~ tion,~ the ring opening of cyclic compounds by regioselective CC bond fi~ sion,~ and the formation of cyclic Also, by such reactions alkoxy radicals act as initiators for vinyl polymerization and ...