Selective monoacylation of 1, n-diols catalyzed by metallic sulfates supported on silica gel

T Nishiguchi, H Taya

Index: Nishiguchi, Takeshi; Taya, Hisashi Journal of the American Chemical Society, 1989 , vol. 111, # 25 p. 9102 - 9103

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Citation Number: 49

Abstract

It is important for organic synthesis to establish general methods for selective and differential functionalization of the same kind of plural functional groups having similar stereoelectronic and steric factors. Monoprotection or monofunctionalization of polyols is achieved in some cases by carefully controlled reaction conditions,'by continuous extraction, 2 by the use of alumina3 and insoluble polymer supports: or via cyclic compound f~ rmation.~ In the ...