The entrapment of chiral guests with gated baskets: can a kinetic discrimination of enantiomers be governed through gating?
…, S Stojanović, DA Turner, TL Young…
Index: Wang, Bao-Yu; Stojanovic, Sandra; Turner, Daniel A.; Young, Tanya L.; Hadad, Christopher M.; Badjic, Jovica D. Chemistry - A European Journal, 2013 , vol. 19, # 15 p. 4767 - 4775
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Citation Number: 11
Abstract
Abstract The capacity of gated hosts for controlling a kinetic discrimination between stereoisomers is yet to be understood. To conduct corresponding studies, however, one needs to develop chiral, but modular and gated hosts. Accordingly, we used computational (RI-BP86/TZVP//RI-BP86/SV (P)) and experimental (NMR/CD/UV/Vis spectroscopy) methods to examine the transfer of chirality in gated baskets. We found that placing stereocenters of ...
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