Inorganica Chimica Acta

DNA/protein interaction and cytotoxicity of palladium (II) complexes of thiocarboxamide ligands

E Sindhuja, R Ramesh, N Dharmaraj, Y Liu

Index: Sindhuja, Elangovan; Ramesh, Rengan; Dharmaraj, Nallasamy; Liu, Yu Inorganica Chimica Acta, 2014 , vol. 416, p. 1 - 12

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Citation Number: 13

Abstract

Abstract Four planar palladium (II) complexes with general formula [Pd (Cl)(L)(PPh 3)](HL= N-substituted pyridine-2-thiocarboxamide) have been synthesized and characterized by analytical, spectral (IR, UV–Vis and 1 H, 13 C and 31 P NMR) and single crystal X-ray methods. Crystal structure of all the complexes indicated a mono negative bidentate coordination of thiocarboxamide ligands to the palladium center via pyridine nitrogen and ...