Terminally perfluorinated long-chain alkanethiols

…, VY Wang, GM Nassif, R Colorado, RJ Villazana…

Index: Graupe, Michael; Koini, Thomas; Wang, Vincent Y.; Nassif, George M.; Colorado Jr, Ramon; Villazana, Ramon J.; Dong, Henry; Miura, Yasuhiro F.; Shmakova, Olga E.; Lee, T. Randall Journal of Fluorine Chemistry, 1999 , vol. 93, # 2 p. 107 - 115

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Citation Number: 63

Abstract

This paper describes the synthesis of a series of alkanethiols containing perfluorinated terminal segments: F (CF2) m (CH2) nSH, where m= 1, n= 9–15; m= 2, n= 11–14; m= 3, n= 10–13; and m= 4, n= 9–12. Fluorinated alkyl iodides of the general formula F (CF2) m (CH2) nI, where m= 1–4 and n= 0 or 1, were added to long-chain ω-olefins that were functionalized at the α-terminus with a thioacetate group. The reactions proceeded in good yields under ...