Indium-Mediated One-Pot Three-Component Reaction of Aromatic Amines, Enol Ethers, and Allylic Bromides
…, MS Jang, G Keum, SB Kang, BY Chung, Y Kim
Index: Jang, Taeg-Su; Keum, Gyochang; Kang, Soon Bang; Chung, Bong Young; Kim, Youseung Synthesis, 2003 , # 5 p. 775 - 779
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Citation Number: 12
Abstract
We wish to disclose herein an efficient indium-mediated one-pot three-component reaction for the synthesis of N-aryl-substituted homoallylamines from aromatic amines, enol ethers, and allylic bromides. Thus treatment of allylic indium compounds, generated in situ from allyl bromides and indium powder, with aromatic amines and enol ethers in THF at room temperature under argon for 2−24 h resulted in the formation of the corresponding homoallylic amine ...
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