Synthesis and characterization of novel phthalocyanines with four tridentate NNS substituents and four chloro groups

Ş Merey, Ö Bekaroǧlu

Index: Merey, Sebnur; Bekaroglu, Oezer Journal of the Chemical Society - Dalton Transactions, 1999 , # 24 p. 4503 - 4510

Full Text: HTML

Citation Number: 28

Abstract

Two new 4, 5-disubstituted phthalonitrile derivatives have been prepared from tridentate amine thiol reactants obtained by reducing directly two different benzothiazolines. Novel metal free phthalocyanines and divalent metal phthalocyanines carrying four tridentate NNS substituents in addition to four chloro groups on peripheral positions have been synthesized from the corresponding phthalonitrile derivatives in the presence of a suitable anhydrous ...