The free radical addition of phosphines to unsaturated compounds

MM Rauhut, HA Currier, AM Semsel…

Index: Rauhut,M.M. et al. Journal of Organic Chemistry, 1961 , vol. 26, p. 5138 - 5145

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Citation Number: 107

Abstract

the second step occurs with considerable ease. The reaction of phosphine with ethyl acrylate, however, did give a 4: 1 acrylate-phosphine adduct in addition to the three expected organophosphine products. The 4: l adduct appeared to be identical (boiling point, infrared spectrum, NMR spectrum, index of refraction, and elemental analysis) with bis (2- carbethoxyethyl)-2, 4-dicarbethoxybutylphos-phine, prepared unambiguously by the ...