Microwave assisted hydroaminomethylation of alkenes
E Petricci, A Mann, J Salvadori, M Taddei
Index: Petricci, Elena; Mann, Andre; Salvadori, Jessica; Taddei, Maurizio Tetrahedron Letters, 2007 , vol. 48, # 48 p. 8501 - 8504
Full Text: HTML
Citation Number: 25
Abstract
Hydroaminomethylation of terminal alkenes can be regioselectively carried out in less than 30min with secondary amines in EtOH under MW irradiation using (PPh3) 3RhCO (H) and Xantphos or Biphephos as ligands. When primary amines were employed, the corresponding enamines were obtained in good yields. Tris-benzyl allylglycine was transformed into different (basic) benzylated α-amino acids. Moreover, the benzyl ...
Related Articles:
Efficient and regioselective ruthenium-catalyzed hydro-aminomethylation of olefins
[Wu, Lipeng; Fleischer, Ivana; Jackstell, Ralf; Beller, Matthias Journal of the American Chemical Society, 2013 , vol. 135, # 10 p. 3989 - 3996]
Catalytic hydrogenation of amides to amines
[Wojcik; Adkins Journal of the American Chemical Society, 1934 , vol. 56, p. 2419,2422]
Catalytic hydrogenation of amides to amines
[Wojcik; Adkins Journal of the American Chemical Society, 1934 , vol. 56, p. 2419,2422]
Formation of Acetals under Rhodium??Catalyzed Hydroformylation Conditions in Alcohols
[Diebolt, Olivier; Cruzeuil, Clement; Mueller, Christian; Vogt, Dieter Advanced Synthesis and Catalysis, 2012 , vol. 354, # 4 p. 670 - 677]
α-Metallierte amine durch deprotonierung aliphatischer N-methylamine
[Ahlbrecht, Hubertus; Dollinger, Horst Tetrahedron Letters, 1984 , vol. 25, # 13 p. 1353 - 1356]