Synthesis of nitrosubstituted triangulanes
OA Ivanova, NV Yashin, EB Averina, YK Grishin…
Index: Ivanova; Yashin; Averina; Grishin; Kuznetsova; Zefirov Russian Chemical Bulletin, 2001 , vol. 50, # 11 p. 2101 - 2105
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Citation Number: 10
Abstract
Abstract The [1+ 2] cycloaddition of ethyl nitrodiazoacetate to various methylenecyclopropanes afforded 1-ethoxycarbonyl-1-nitropolyspirocyclopropanes. These compounds were used in the synthesis of first representatives of nitrosubstituted triangulanes. Nitrospiropentane was prepared also by dehydrohalogenation of 1- bromomethyl-1-(nitromethyl) cyclopropane.
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