Selective Hydroformylation of Internal Acetylenes by PdCl2 (PCy3) 2: Remarkable Synergistic Effect of Cobalt1

…, K Miyashita, K Kamita, M Hidai

Index: Ishii; Miyashita; Kamita; Hidai Journal of the American Chemical Society, 1997 , vol. 119, # 27 p. 6448 - 6449

Full Text: HTML

Citation Number: 64

Abstract

We have long been interested in development of homogeneous heterobimetallic catalyst systems composed of two different metal complexes which might be used for unique organic synthesis. During our continuing study toward this direction, we have developed several mixed-metal catalyst systems for various types of carbonylation reactions including the homologation of methanol, 2 hydroformylation of olefins, 3 formylation of iodoarenes, 4 ...

Related Articles:

Rhodium??katalysierte Hydroformylierung innerer Alkine zu α, β??ungesättigten Aldehyden

[Johnson, John R.; Cuny, Gregory D.; Buchwald, Stephen L. Angewandte Chemie, 1995 , vol. 107, # 16 p. 1877 - 1879]

A further breakthrough in biphasic, rhodium-catalyzed hydroformylation: the use of Per (2, 6-di-O-methyl)-β-cyclodextrin as inverse phase transfer catalyst

[Monflier, Eric; Tilloy, Sebastien; Fremy, Georges; Castanet, Yves; Mortreux, Andre Tetrahedron Letters, 1995 , vol. 36, # 52 p. 9481 - 9484]

A new method for the alkylation of ketones and aldehydes: the C-alkylation of the Magnesium salts of N-substituted imines

[Stork,G.; Dowd,S.R. Journal of the American Chemical Society, 1963 , vol. 85, p. 2178 - 2180]

Remarkable Effect of the Wavelength in the Photoassisted Carbonylation of the C–H Bond of Decane in the Presence of RhCl (CO)(PR 3) 2 as the Catalyst

[Sakakura, Toshiyasu; Sasaki, Koushi; Tokunaga, Yuko; Wada, Keisuke; Tanaka, Masato Chemistry Letters, 1988 , p. 155 - 158]

Direct conversion of nitriles to. alpha.-alkylated aldehydes

[Goering, Harlan L.; Tseng, Chung Chyi Journal of Organic Chemistry, 1981 , vol. 46, p. 5250 - 5252]

More Articles...