Steric influence on hapto interactions in supramolecularly linked thallium dithiocarbamates

K Ramalingam, C Rizzoli, N Alexander

Index: Ramalingam, Kuppukkannu; Rizzoli, Corrado; Alexander, Nagarajan Monatshefte fur Chemie, 2013 , vol. 144, # 9 p. 1329 - 1334

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Citation Number: 4

Abstract

Abstract Spectral and structural characterization of diallyl and dibenzyl dithiocarbamates of thallium (I) indicated increased thalliocarbon hapto interactions in dibenzyl dithiocarbamate due to increased steric effects. Proton magnetic resonance spectra of the compounds showed that the protons in the vicinity of the thioureide nitrogen are highly deshielded and the corresponding 13 C spectra showed large chemical shifts of the thioureide carbons ...