Synthesis

The photo-dehydro-Diels-Alder (PDDA) reaction-A powerful method for the preparation of biaryls

P Wessig, G Mueller, C Pick, A Matthes

Index: Wessig, Pablo; Mueller, Gunnar; Pick, Charlotte; Matthes, Annika Synthesis, 2007 , # 3 p. 464 - 477

Full Text: HTML

Citation Number: 11

Abstract

Abstract The photochemically initiated dehydro-Diels-Alder (PDDA) reaction is an efficient and versatile method for the preparation of biaryls. The ring closure may take place both inter-and intramolecularly, of which the intramolecular variant is more productive from the preparative point of view. A variety of linkers can be employed to connect the ynone moiety, which acts as the chromophore, with another acetylene group, thus allowing large ...