First B-organyloxy-substituted iminoboranes: Preparation, stabilization, and reactivity

…, G Elter, M Noltemeyer, HG Schmidt, A Meller

Index: Elter, Gernot; Neuhaus, Michael; Meller, Anton; Schmidt-Baese, Dieter Journal of Organometallic Chemistry, 1990 , vol. 381, # 3 p. 299 - 313

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Citation Number: 46

Abstract

2, 6-Disubstituted aryloxyiminoboranes, ArxOB⋮ NBut (Arx= 2, 6-But2C6H3 or 2, 6- Ph2C6H3), were obtained by treatment of ArxOB (Cl) N (H) But with tBuLi in hexane at-78° C. These intermediates are detected by 11B NMR and confirmed by insertion reactions with

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