Inorganica chimica acta

Coordination chemistry of organometallic bases of group IV elements. Part IV: 2: 1 adducts of antimony (V) chloride and μ-oxo-bis [triorganotin (IV)] compounds.

SP Narula, N Kapur, RK Sharma

Index: Narula, Suraj P.; Kapur, Neeta; Sharma, Ramesh K. Inorganica Chimica Acta, 1984 , vol. 85, p. 37 - 40

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Abstract

Abstract Two mol of antimony (V) chloride and one mol of μ-oxo-bis [tri-n-propyl/tri-n-butyl or triphenyl tin (IV)] compound (L) react in carbon tetrachloride and/or dichloromethane at ice water temperature to give solid compounds of composition L· 2SbCl 5. Elemental analyses, molar conductances, infrared spectral data, as well as metathetical reactions with silver nitrate and silver perchlorate in acetonitrile solution, point to the ionic structure [(R 3 Sn) 2 ...