Absolute rate constants for the reactions of some carbon-centered radicals with 2, 2, 6, 6-tetramethyl-1-piperidinoxyl

J Chateauneuf, J Lusztyk, KU Ingold

Index: Chateauneuf, J.; Lusztyk, J.; Ingold, K. U. Journal of Organic Chemistry, 1988 , vol. 53, # 8 p. 1629 - 1632

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Citation Number: 263

Abstract

Results The carbon-centered radicals were generated by laser flash photolysis (LFP) of appropriate precursors. These included symmetrically substituted ketones (eq 2), diacyl peroxides (eq 3), and di-tert-butyl peroxide in the presence of a hydrogen donating substrate (eq 4 and 5);