Tetrahedron letters

Organic Synthesis with Sulfones noXXIX Stereospecific hydrogenolysis of vinylic sulfones with grignards and transition metal catalysts.

JL Fabre, M Julia

Index: Fabre, J.-L.; Julia, M. Tetrahedron Letters, 1983 , vol. 24, # 40 p. 4311 - 4314

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Citation Number: 48

Abstract

Hydrogenolysis of various vinylic sulfones to the corresponding olefins can be carried out by alkyl Grignard reagents with nickel or palladium catalysts. Yields are good to excellent. Retention of configuration is observed. The influence of ligands is discussed. ... ☆ Organic synthesis with sulfones n o XXVIII, M. Julia, D. Lave, M. Mulhauser, M. Ramirez-Munoz and D. Uguen, Tetrahedron Letters, 1983, 24, 1783. ... Couplage mixte entre sulfones vinyliques et réactifs de ...