Tetrahedron

Photochemical behaviour of 3.4-epoxyprecocene-I and related epoxychromans

G Ariamala, KK Balasubramanian

Index: Ariamala, G.; Balasubramanian, K. K. Tetrahedron, 1989 , vol. 45, # 12 p. 3769 - 3774

Full Text: HTML

Citation Number: 5

Abstract

A systematic study of photochemical behaviour of 3, 4-epoxyprecocene-I and related epoxychromans was undertaken. Upon irradiation in acetone or cyclohexane, 3, 4- epoxyprecocene-I 1 was found to undergo photoisomerisation to the corresponding 3- chromanone 2. In contrast, the photochemical behaviour of analogous 3, 4-dihydro-3, 4- epoxy-2H-1-benzopyrans 3 was found to be dependent upon the nature of solvent. ...

Related Articles:

Synthesis and insect antifeedant activity of precocene derivatives with lactone moiety

[Szczepanik, Maryla; Obara, Robert; Szumny, Antoni; Gabrys, Beata; Halarewicz-Pacan, Aleksandra; Nawrot, Jan; Wawrzenczyk, Czeslaw Journal of Agricultural and Food Chemistry, 2005 , vol. 53, # 15 p. 5905 - 5910]

Comment on cube resin insecticide: identification and biological activity of 29 rotenoid constituents

[Anastasis, Panayiotis; Brown, Philip E. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 7 p. 1431 - 1437]

Kinetics and mechanism of solvolysis of Precocene I 3, 4-oxide: change in rate-determining step and trapping of an intermediate in an epoxide solvolysis reaction

[Sayer, J. M.; Grossman, S. J.; Adusei-Poku, K. S.; Jerina, D. M. Journal of the American Chemical Society, 1988 , vol. 110, # 15 p. 5068 - 5074]

Improved procedure for the preparation of 3, 4??dihydro??2, 2??dimethyl??2H??1??benzopyran??3??ones

[Camps, F.; Colomina, O.; Conchillo, A.; Messeguer, A. Journal of Heterocyclic Chemistry, 1985 , vol. 22, p. 1421 - 1423]

Comment on cube resin insecticide: identification and biological activity of 29 rotenoid constituents

[Anastasis, Panayiotis; Brown, Philip E. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 7 p. 1431 - 1437]

More Articles...