Palladation and subsequent functionalization at the second peri position of 1-substituted naphthyl groups

…, N Sutter-Beydoun, A De Cian, J Fischer

Index: Pfeffer, Michel; Sutter-Beydoun, Nohma; Cian, Andre De; Fischer, Jean Journal of Organometallic Chemistry, 1993 , vol. 453, # 1 p. 139 - 146

Full Text: HTML

Citation Number: 37

Abstract

Abstract The cyclopalladation of ligands having a naphthyl group substituted at the 1- position by either amino or imino units has been studied. Palladation of the naphthyl unit occurs as expected at the second peri position of the N, N-dialkylamino substituted derivatives. However, the imines were not palladated at the 8-position of the naphthyl unit. The last ligands were synthesized by condensation of either acetone or acetophone on Pd ...