Generation and reactivity of a 3H-phosphaindene: the first 3H-phosphole
RA Aitken, PN Clasper, NJ Wilson
Index: Aitken, R. Alan; Clasper, P. Nicholas; Wilson, Neil J. Tetrahedron Letters, 1999 , vol. 40, # 28 p. 5271 - 5274
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Citation Number: 8
Abstract
Preparation of5: Using the equipment for flash vacuum pyrolysis as described previously, [7] the furnace tube was filled with a 5 cm bed of anhydrous sodium carbonate between glass wool plugs and and heated at 400 °C and 10 −3 Torr for 2 h. The inlet tube containing 3 (ref. 3) (0.66 g) was then attached and the pyrolysis carried out at 400 °C and 10 −3 Torr for 1 h. The system was isolated from the vacuum and filled with dry nitrogen. The cold trap was allowed to ...
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