Phosphorus and Sulfur and the Related Elements

ZUR SYNTHESE VON ALKYLTHIO-, CYCLOALKYLTHIO-UND CYCLOALKYLDISULFIDEN DURCH OXIDATION VON MERCAPTOTHIOETHERN, BIS-MERCAPTO- …

E Weissflog

Index: Weissflog, Eckhard Phosphorus and Sulfur and the Related Elements, 1983 , vol. 15, p. 27 - 32

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Abstract

Abstract The treatment of mercaptothioethers CH3 (SCH2) nSH, n= 1, 2, 1, 2 with equivalent amounts of iodine and triethyl amine leads to the formation of 2.4. 5.7-tetrathiaoctane 3 and 2.4. 6.7. 9.11-hexathiadodecane 4. Oxidation of ethanedithiol-1.2 5 leads to polyethylene disulfide 6, 1.2. 5.6-tetrathiacyclooctane 7 and 1.2. 5.6. 9.10. 13.14- octathiacyclohexadecane 8, whereas bis-(mercaptomethyl)-sulfide 9 is converted to ...