Activation of Sn-Se bond: Regioselective ring opening reaction of epoxides with tributylstannyl phenylselenolate in the presence of a Lewis acid
Y Nishiyama, H Ohashi, K Itoh, N Sonoda
Index: Nishiyama, Yutaka; Ohashi, Hironori; Itoh, Kazuyoshi; Sonoda, Noboru Chemistry Letters, 1998 , # 2 p. 159 - 160
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Citation Number: 22
Abstract
抄録 When tributylstannyl phenylselenolate (Bu< SUB> 3 SnSePh) was allowed to react with epoxides in the presence of BF< SUB> 3· OEt< SUB> 2 as a Lewis acid, the ring opening reaction of epoxides proceeded with complete regioselectivity to afford the β-hydroxy phenylselenides in moderate to good yields.
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