Journal of Organometallic Chemistry

Synthese und dynamisches verhalten von einigen pentamethylcyclopentadienylsilanen und-germanen

P Jutzi, H Saleske, D Bühl, H Grohe

Index: Jutzi, Peter; Saleske, Hartmut; Buehl, Dittmar; Grohe, Hildegard Journal of Organometallic Chemistry, 1983 , vol. 252, # 1 p. 29 - 36

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Abstract

Abstract By reaction of pentamethylcyclopentadienyllithium (pcpLi) with the corresponding chloro-silanes and-germanes, the h 1-pcp-silanes and-germanes I–IX are synthesized. Nucleophilic substitution reactions at the pcp-chlorogermane VII lead to the h 1-pcp- germanes X–XIII. The activation parameters for the sigmatropic rearrangements in these compounds have been evaluated from the 1 H DNMR data. They show little influence of ...