Unusual reaction of chloroacetyl chloride with 1, 2-dichloro-ethylene. Synthesis of 1, 1, 4-trichlorobut-3-en-2-one
…, EV Rudyakova, AN Mirskova, GG Levkovskaya
Index: Bozhenkov; Savosik; Rudyakova; Mirskova; Levkovskaya Russian Journal of Organic Chemistry, 2008 , vol. 44, # 1 p. 146 - 147
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Abstract
Chlorovinyl ketones are very important and promising synthons for the preparation of various highly reactive polyfunctionalized compounds, including heterocyclic ones [1]. We previously synthesized alkyl 1, 2-dichlorovinyl ketones from aliphatic carboxylic acid chlorides and 1, 2-dichloroethylene in the presence of aluminum chloride [2]. While continuing studies on the scope of application of the proposed procedure for the ...
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